Table 3.
Fitting parameters for the LF fits to the adsorption isotherms of MIPs.
| DS-MIP | D-MIP | S-MIP | |
|---|---|---|---|
| D | |||
| Nt | 3.64 ± 0.01 μmol/g | 2.76 ± 0.19 μmol/g | 10.27 ± 0.66 μmol/g |
| a | 3.30 ± 0.01 mM−1 | 3.44 ± 0.05 mM−1 | 1.02 ± 0.12 mM−1 |
| Ko | 4.17 ± 0.01 mM−1 | 4.48 ± 0.04 mM−1 | 1.03 ± 0.16 mM−1 |
| m | 0.84 ± 0.01 | 0.83 ± 0.03 | 0.75 ± 0.02 |
| Limits of affinity distribution* | 0.09–9.5 mM−1 | 0.09–9.5 mM−1 | 0.19–9.5 mM−1 |
| R2 | 0.998 | 0.966 | 0.975 |
| S | |||
| Nt | 5.86 ± 0.01 μmol/g | 46.54 ± 16.81 μmol/g | 5.00 ± 0.37 μmol/g |
| a | 4.73 ± 0.08 mM−1 | 0.07 ± 0.01 mM−1 | 4.02 ± 0.16 mM−1 |
| Ko | 12.85 ± 1.09 mM−1 | 0.03 ± 0.001 mM−1 | 8.08 ± 0.36 mM−1 |
| m | 0.61 ± 0.02 | 0.82 ± 0.02 | 0.67 ± 0.01 |
| Limits of affinity distribution* | 0.21–25.0 mM−1 | 0.19–9.5 mM−1 | 0.20–14.18 mM−1 |
| R2 | 0.976 | 0.993 | 0.997 |
*.
These limits were calculated from the maximum and minimum values of free guest concentration (Fmax and Fmin) by the relationships Kmin =1/Fmax and Kmax =1/Fmin.