Table 5. Negishi Reactions of Aryl Chlorides Catalyzed by Pd/P(t-Bu)3.
![]() | |||
|---|---|---|---|
| entry | aryl chloride | ClZn-R | yield (%) |
| 1 | ![]() |
![]() |
94 |
| 2 | ![]() |
![]() |
87 |
| 3 | ![]() |
![]() |
92 |
| 4 | ![]() |
![]() |
89 |
| 5 | ![]() |
![]() |
91 |
| 6 | ![]() |
![]() |
76 |
| 7 | ![]() |
ClZn-n-Bu | 83 |
![]() | |||
|---|---|---|---|
| entry | aryl chloride | ClZn-R | yield (%) |
| 1 | ![]() |
![]() |
94 |
| 2 | ![]() |
![]() |
87 |
| 3 | ![]() |
![]() |
92 |
| 4 | ![]() |
![]() |
89 |
| 5 | ![]() |
![]() |
91 |
| 6 | ![]() |
![]() |
76 |
| 7 | ![]() |
ClZn-n-Bu | 83 |