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. Author manuscript; available in PMC: 2009 Nov 18.
Published in final edited form as: Acc Chem Res. 2008 Nov 18;41(11):1555–1564. doi: 10.1021/ar800148f

Table 7. Room-Temperature Heck Reactions of Aryl Bromides Catalyzed by Pd/P(t-Bu)3.

graphic file with name nihms-86549-t0107.jpg
entry aryl bromide olefin product yield (%)
1 graphic file with name nihms-86549-t0108.jpg graphic file with name nihms-86549-t0109.jpg graphic file with name nihms-86549-t0110.jpg 77
2 graphic file with name nihms-86549-t0111.jpg graphic file with name nihms-86549-t0112.jpg graphic file with name nihms-86549-t0113.jpg 80
3 graphic file with name nihms-86549-t0114.jpg graphic file with name nihms-86549-t0115.jpg graphic file with name nihms-86549-t0116.jpg 83

E:Z selectivity: 10:1 for entry 1; >20:1 for entries 2 and 3.