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. Author manuscript; available in PMC: 2009 Dec 1.
Published in final edited form as: Inorg Chem. 2008 Dec 1;47(23):10875–10888. doi: 10.1021/ic8009817

Table 3.

Spectroscopic values for Cd(II)/TRILXC complexes.

System UV-Visa 113Cd NMRb 111mCd PAC
λmax (nm) Δε Δ (ppm) ω0 (rad/ns) η
TRI L16Cc 232 22600 625 0.337
0.438		 0.23
0.20
TRI L12AL16Cd 230 21800 574 0.341 0.141
TRI L16Pend 227 28900 684 0.454 0.02
TRIL12CL16C 222
sh 238		 16250
14920		 560 0.380(1)
0.270(14)		 0.486(5)
0.50(7)
TRIL9CL12C 227
sh 240		 20200
17800		 650
680		 0.14(4) 1(1)
CmtRe 240 ≈16000 480 0.291(1) 0.18(1)
a

λ given in nm and Δε given as M−1 cm−1.

b

Chemical shift reported versus Cd(ClO4)2.

c

Data from Reference 29.

d

Data from Reference 17.

e

Data from Reference 30.