Table 3. Kinetic Parameters for H115W−dNTP Binding.
| k1 (×106 M−1 s−1) | k−1 (s−1) | Kd (μM)a | |
|---|---|---|---|
| dCTP | 0.055 ± 0.001 | 0.51 ± 0.001 | 9.3 ± 0.2 |
| dGTP | 0.17 ± 0.002 | 0.12 ± 0.0004 | 0.71 ± 0.01 |
| dATP | 0.18 ± 0.003 | 0.11 ± 0.0005 | 0.61 ± 0.01 |
| dTTP | 0.050 ± 0.001 | 0.75 ± 0.002 | 15 ± 0.3 |
k1 was calculated as the slope of the linear fit of rate of dNTP binding as a function of dNTP concentration. k−1 was obtained from a single-exponential fit of the fluorescence change upon dNTP release in the presence of 20 mM EDTA. KD was calculated as k−1/k1.