Table 1.
Comparison of the average number of ligands per dendrimer independently computed by NMR and HPLC techniques with the three statistical models.
| NMR Average | HPLC Averagea | Poisson I (χ2 = 66)b | Poisson II (χ2 = 47) | Two Path (χ2 = 9) | |
|---|---|---|---|---|---|
| Sample A | 0.20 ± 0.02 | 0.20 ± 0.01 | 0.20 | 0.21 | 0.21 |
| Sample B | 0.60 ± 0.06 | 0.54 ± 0.02 | 0.60 | 0.53 | 0.54 |
| Sample C | 1.04 ± 0.10 | 0.98 ± 0.04 | 1.04 | 0.91 | 0.93 |
| Sample D | 1.47 ± 0.15 | 1.45 ± 0.06 | 1.47 | 1.17 | 1.32 |
a
Determination of HPLC error is discussed in the Experimental Methods section of the Supporting Information.
b
The Poisson I model uses the experimental NMR averages as input parameters.