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. Author manuscript; available in PMC: 2009 Dec 1.
Published in final edited form as: J Inorg Biochem. 2008 Aug 6;102(12):2103–2113. doi: 10.1016/j.jinorgbio.2008.07.016

Table 4.

Selected metrical parameters for [CuII(KH)O]+, [CuII(KH)N]+, [CuII(H–KH)N]+, and [CuII(GKH)]+.

[CuII(KH)O]+ [CuII(KH)N]+ [CuII(H-KH)N]+ [CuII(GKH)]+
Cu-NIm 1.948 Å 1.913 Å 1.907 Å 1.978 Å
Cu-Namide 1.985 Å 1.949 Å 1.951 Å 1.946 Å
Cu-O/Cu-N 1.929 Å 1.881 Å 1.879 Å 1.928 Å
Cu-S/Cu-O 2.344 Å 3.592 Å 3.586 Å 2.078 Å
S/O-Cu-Namide 159.4° 153.9° 155.4° 170.7°
NIm-Cu-O/N 162.6° 172.6° 171.5° 168.0°
NIm-Cu-Namide 98.7° 97.1° 96.8° 92.6°
Namide-Cu-N/O 98.3° 84.7° 84.8° 84.4°
N/O-Cu-S/O 72.4° 104.2° 102.7° 99.1°
S/O-Cu-NIm 92.5° 77.3° 79.3°å 85.6°