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ORTEP of reduced [FeII((tame—N3)S2Me2)(CO)]•MeCN (16), the cations of [FeIII((tame—N3)S2Me2)(NO)](PF6) (18) and [FeIII((tame—N3)S2Me2)(MeCN)](PF6)•MeCN (19) showing 50% ellipsoids and atom labeling scheme, as well as the weakly interacting MeCN (Fe—N(4)= 2.63 Å) in 19.