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Redox Potential Dependence on Ligand Environment and Molecular Charge.
| Compound | Reduction Potential (vs SCE) |
|---|---|
| [FeIII((tame—N3)S2Me2)]+ (1) | −650 mV |
| [FeIII(DITIm)2]+ | −680 mV |
| [FeIII(DITpy)2]+ | −930 mV |
| [FeIII(ADIT)2]+ | −1002 mV |
| [FeIII(Et—N2S2Me2)]22- (2) | −1130 mV |
| [FeIII(Et—N2S2Me2)(Py)]1- (3) | −1340 mV |
| [FeIII((tame—N2S)S2Me2)]2- (15) | < -1800 mV |
