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. Author manuscript; available in PMC: 2010 Feb 25.
Published in final edited form as: J Am Chem Soc. 2009 Feb 25;131(7):2621–2628. doi: 10.1021/ja807847q

Figure 1.

Figure 1

Kinetic traces. (A) Reaction of 1a (2 × 10−5 M) with Fe(ClO4)3 (5 × 10−4 M) in acetonitrile at room temperature monitored at 396 nm; the iron(IV) complex 2a was formed in 0.3 s and decayed to 3a. (B) Laser irradiation of 2b monitored at 403 nm; the pre-trigger sequence was initiated (t = 0 ms) at 0.2 s after mixing, and the laser fired ca. 50 ms later.