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. 2009 Apr 10;284(15):9713–9726. doi: 10.1074/jbc.M807866200

TABLE 2.

Chemical shift data (ppm) for anomeric resonances from proton NMR spectra of glycosphingolipids from blood group A and O pig intestinal epithelia, obtained in DMSO-d6/D2O (98:2, by volume) at 30 °C

IX VIII VII VI V IV III II I Trivial name Reference
Fucα2 Galβ3 GlcNAcβ3 Galβ4 Glcβ1 Cer H5 type1 This work and Ref. 39
4.983 4.442 4.574 4.262 4.207
GalNAcα3 (Fucα2) Galβ3 GlcNAcβ3 Galβ4 Glcβ1 Cer A6 type 1 This work and Ref. 39
4.913 5.061 4.501 4.532 4.259 4.208
GalNAcα3 (Fucα2) Galβ3 GalNAcβ3 Galα4 Galβ4 Glcβ1 Cer A7 type 4 This work and Ref. 40
4.930 5.056 4.510 4.437 4.810 4.253 4.208
GalNAcα3 (Fucα2) Galβ3 GlcNAcβ3 Galβ3 GlcNAcβ3 Galβ4 Glcβ1 Cer A8 type 1 This work and Ref. 41
4.917 5.066 4.49 4.53 4.18 4.78 4.26 4.21
GalNAcα3 (Fucα2) Galβ3 GalNAcα3 (Fucα2) Galβ3 GlcNAcβ3 Galβ4 Glcβ1 Cer A9 type 1 This work
4.948 5.055 4.657 4.932 5.276 4.469 4.50 4.26 4.21
GalNAcα3 (Fucα2) Galβ3 GalNAcα3 (Fucα2) Galβ4 GlcNAcβ3 Galβ4 Glcβ1 Cera A9 type 3 From Ref. 42
4.947 5.061 4.663 4.955 5.329 4.344 4.618 4.260 4.168
a

Measured at 35 °C except for the anomeric resonances stemming from the GalNAcα3 residues and the internal Fucα2, which were obtained at 55 °C (42).