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. Author manuscript; available in PMC: 2010 Apr 2.

Published in final edited form as: J Phys Chem B. 2009 Apr 2;113(13):4248–4256. doi: 10.1021/jp810685g

204-nm excited UVRR spectra of PNIPAM at (A) 4 °C and (B) 45 °C the spectra were decomposed into a minimum sum of mixed Lorentzian and Gaussian bands. The AmI region was fit to Gaussian bands. The measured and modeled spectra overlap almost completely. The different amide-hydrogen bonding sites are shown in the Fig 5A insert.

204-nm excited UVRR spectra of PNIPAM at (A) 4 °C and (B) 45 °C the spectra were decomposed into a minimum sum of mixed Lorentzian and Gaussian bands. The AmI region was fit to Gaussian bands. The measured and modeled spectra overlap almost completely. The different amide-hydrogen bonding sites are shown in the Fig 5A insert.