. Author manuscript; available in PMC: 2010 Jan 1.

Published in final edited form as: Organometallics. 2009;28(5):1350–1357. doi: 10.1021/om800986s

Table 3.

Electrochemical Potentials (V vs. FeCp₂^+/0) in CH₂Cl₂/0.1 M ⁿBu₄NPF₆ for 1–6 and Related Compounds.

	1	2	3	4	5	6	IX	Fe(C₅Me₄H)₂	RuCp₂
E_1/2^+/0	+0.16	−0.25	+0.31^a	+0.15	−0.21	+0.41^a	+0.37^b	−0.45^c	+0.56^a
E_1/2^0/−	−1.21^b	−1.34^b	−1.24^b	−0.89^b	−0.96^b	−0.88^b	−0.93^b	–	–

Irreversible; values given are peak potentials, E_ox, at 50 mVs⁻¹.

EC-type processes.

Data from reference ⁶⁶.