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. Author manuscript; available in PMC: 2009 Sep 18.
Published in final edited form as: J Phys Chem B. 2008 Aug 21;112(37):11827–11837. doi: 10.1021/jp8054679

Table 1.

KD Parameters that Describe the [α(Zn), β(Fe3+N3-)] ET Photocycle.

Parameter Initial Final
kteq (s-1)a 18 21
kbeq (s-1)a 230 210
ktS (s-1)a 5 5
ktR (s-1) 409 517
kbS (s-1) 221 200
kbR (s-1)a 500 550
KS 30 31
α 0.83 0.91
kd0 (s-1) 3000 1017
a

Constraints generated as described in text