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. Author manuscript; available in PMC: 2009 Sep 24.
Published in final edited form as: J Am Chem Soc. 2008 Aug 30;130(38):12680–12689. doi: 10.1021/ja8022434

Figure 8.

Figure 8

Thermochemistry for electron capture by (KYK + 2H)(H2O)n 2+ deduced from ion nanocalorimetry experiments, where the recombination energy is determined from the number of water molecules lost from the reduced precursor (see text). Appearance energies (kcal/mol) relative to the reduced precursor are indicated in parentheses.