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Kinetic and energetic parameters of ABLM reaction with DNA and ABLM self-decay, calculated from CD kinetic data (see Figure 7.)
| Reaction | ABLM + DNA | ABLM decay |
|---|---|---|
| Rate (s−1) | 0.044 ± 0.02 | 0.018 ± 0.003 |
| kH/kD | 1.7 ± 0.2 | 3.6 ± 0.9 |
| Ea (kcal/mol) | 4.7 ± 0.9 | 9.3 ± 0.9 |
| ΔG‡ (kcal/mol) | 19.0 ± 0.02 | 19.5 ± 0.03 |
| ΔH‡ (kcal/mol) | 4.4 ± 1.6 | 9.0 ± 3 |
| ΔS‡ (cal/mol−1K−1) | −48 ± 6 | −36 ± 10 |
