Table 2.
The average enhancement factors for 1,4-BDT and 4-MBT adsorbed on nanocubes of 46 nm in edge lengtha.
| molecule | bandb | mode | nanocube | std. dev. |
|---|---|---|---|---|
| 1,4-BDT | 1561 | 8a Ag | 5.7 × 105 | 5.8 × 103 |
| 1183 | 9a Ag | 4.9 × 105 | 4.4 × 103 | |
| 4-MBT | 1593 | 8a Ag | 6.1 × 105 | 8.4 × 103 |
| 1072 | 7a Ag | 4.4 × 105 | 7.7 × 103 | |
The average EFs were calculated for the 8 a vibrational mode (1561 cm−1) and the 9a vibrational mode (1183 cm−1) of 1,4-benzenedithiol (1,4-BDT); the 8a vibrational mode (1593 cm−1) and the 7a vibrational mode (1072 cm−1) of 4-methyl benzenethiol (4-MBT).
Wavenumber in cm−1.