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. Author manuscript; available in PMC: 2010 Apr 23.
Published in final edited form as: J Phys Chem A. 2009 Apr 23;113(16):3932–3939. doi: 10.1021/jp8101817

Table 2.

The average enhancement factors for 1,4-BDT and 4-MBT adsorbed on nanocubes of 46 nm in edge lengtha.

molecule bandb mode nanocube std. dev.

1,4-BDT 1561 8a  Ag 5.7 × 105 5.8 × 103
1183 9a  Ag 4.9 × 105 4.4 × 103
4-MBT 1593 8a  Ag 6.1 × 105 8.4 × 103
1072 7a  Ag 4.4 × 105 7.7 × 103
a

The average EFs were calculated for the 8 a vibrational mode (1561 cm−1) and the 9a vibrational mode (1183 cm−1) of 1,4-benzenedithiol (1,4-BDT); the 8a vibrational mode (1593 cm−1) and the 7a vibrational mode (1072 cm−1) of 4-methyl benzenethiol (4-MBT).

b

Wavenumber in cm−1.