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. Author manuscript; available in PMC: 2009 Oct 29.
Published in final edited form as: J Am Chem Soc. 2008 Oct 3;130(43):14207–14216. doi: 10.1021/ja8035916

Table 3.

Exponential fits to the stopped-flow kinetic data.

Species Rate of product formation (s−1)a
1Zn-L1 0.92 ± 0.03
ZnZn-L1 17 ± 1
1Co-L1 0.05 ± 0.01
ZnCo-L1 12 ± 1
ZnFe-L1 12 ± 1
1Fe-L1 0.12 ± 0.02
a

rates determined by exponential fitting of the stopped-flow data in Figures 3, 4, and 7.