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Observed half-lives for isomerizations of iron(IV) complexes in acetonitrile.a
| Complex | Temp (°C) | t1/2 (s) |
|---|---|---|
| (TPP)FeIV(ClO4)2 (2a) | 22 | 13 |
| 9 | 20 | |
| 1 | 28 | |
| (TMP)FeIV(ClO4)2 (2b) | 22 | 10 |
| (OEP)FeIV(ClO4)2 (2c) | 22 | 13 |
| (TPFC)FeIV(OTs) (4c) | 22 | 2500 |
| (TPFC)FeIV(ClO3) (4d) | 23 | 15 |
| (BPFMC)FeIV(ClO3) (6d) | 22 | 18 |
For isomerizations of ca. 1 × 10−5 M solutions.
