Table 2.

¹H and ¹³C NMR assignments (ppm from TMS) the undecaprenyl chain in undecaprenyl-phosphate-GalN

Isoprene Unit	Methyl Groups	δC	δH
α		24.2	1.73
β to ω-3		24.4	1.67,7 methyl groups
ω		26.5	1.66,1 methyl groups
ω-1, ω-2		17.0	1.60,1 methyl groups 1.57,1 methyl groups
ω		16.8	1.57,1 methyl groups
Isoprene Unit	Methylene Groups
α		63.9	4.443
α		33.0	2.08
β to ω		27.5	2.04
β to ω-3		33.2	2.02
ω-1 to ω-2		40.6	1.97
Isoprene Unit	Methine Groups
α		122.5	5.384
β to ω-3		125.9	∼5.10
ω to ω-2		124.5	∼5.10
Isoprene Unit	Quaternary Carbons
α		142.3
β to ω-3		137.3
ω to ω-2		136.9

Abbreviations: adj, adjacent in relation to a methine proton of an isoprene unit; likewise, cis and trans are used throughout to designate the configurations of various groups in relation to a methine proton of an isoprene unit, as shown above.