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Asymmetric Hydrovinylation of 1,3-Dienes
| Ligand: |  |
 |
||
|---|---|---|---|---|
| diene | conv. % (sel. %) | %ee (config.) | conv. % (sel. %) | %ee (config.) |
| 110 | >99 (>99) | 85 (R) | >99 (>99) | 96 (S) |
| 111 | >99 (97) | 93 (R) | >99 (>99) | >99 (S) |
| 112 | >99 (99) | 38 (R) | >99 (>99) | 95 (S) |
| 113 | 88 (>99) | <5% | >99 (∼96) | 77 (?) |
