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. 2009 Jun 12;394(7):1869–1877. doi: 10.1007/s00216-009-2871-0

Fig. 5.

Fig. 5

Kinetic analysis of the recovery of the C–O stretching vibration. a The early kinetics (5 μs to 1 ms) exhibit second-order recovery kinetics as shown by the linear behaviour of the plot 1/[Mb] vs time. b The later part of the recovery kinetics display first-order kinetics as shown by the linear behaviour of the plot ln{[Mb]/mM} vs time