TABLE I.
Parameters of the kinetic model
Rate constant | k0 | zk |
ms−1 | e0 | |
α00 | 0.3659 | 0.3965 |
β00 | 0.0001 | 2.5084 |
α10 | 2.9902 | 0.0037 |
β10 | 0.4255 | 1.1015 |
α20 | 0.2586 | 0.0001 |
β20 | 2.4364 | 0.0261 |
The rate constants are given for the model presented in Scheme 1. Forward and backward rate constants are α and β, respectively, and follow exponential voltage dependence as α0 = α00exp(z0fVmF/RT) and β0 = β00exp(z0bVmF/RT). The k0 column gives each of the rates at 0 mV, and the zk column indicates the equivalent valence in electronic charge units assigned to the transition. F is the Faraday constant, Vm is voltage, R is the universal gas constant, and T is the temperature in Kelvin.