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. Author manuscript; available in PMC: 2009 Jul 27.
Published in final edited form as: Chem Commun (Camb). 2008 Aug 27;(1):20–33. doi: 10.1039/b809676g

Table 13.

Vinylation of aryl bromides using 19

graphic file with name nihms92008t13.jpg

Entry R t/h Yield (%)
1 4-C(O)Me 3 91
2 4-COOEt 5 83
3 2-COOEt 5 86
4 a 3 71
5 b 3 81
6 2-Et 17 75
7 2,4,6-Me3 48 72
8 4-OMe 10 86
9 2-OMe 20 80
10 4-CH2OH 14 54
11 2-NO2 2 85
12 4-NHAc 12 77
13 2-NMe2 24 74
14 c 3 89
a

1-Bromonaphthalene.

b

2-Bromonaphthalene.

c

3-Bromoquinoline.