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. Author manuscript; available in PMC: 2009 Jul 27.
Published in final edited form as: Chem Commun (Camb). 2008 Aug 27;(1):20–33. doi: 10.1039/b809676g

Table 2.

Vinylation of aryl bromides using vinylboronic acid (5)

graphic file with name nihms92008t2.jpg
Entry R Pd (mol%) Yield (%)
1 4-t-Bu 0.4 87
2 4-NMe2 1.0 89
3 4-MeC(O) 0.1 85
4 4-MeC(O) 0.01 24
5 4-HC(O) 0.4 100
6 4-CN 0.4 100
7 a 0.4 80
8 2-MeC(O) 0.1 84
9 2-HC(O) 1.0 85
10 2-CN 0.4 87
11 2,4,6-Me3 0.4 88
12 2,4,6-i-Pr3 5.0 22
13 b 0.1 87
a

2-Bromo-6-methoxynaphthalene

b

3-Bromoquinoline.