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. Author manuscript; available in PMC: 2009 Jul 27.
Published in final edited form as: Chem Commun (Camb). 2008 Aug 27;(1):20–33. doi: 10.1039/b809676g

Table 6.

Vinylation using potassium vinyltrifluoroborate

graphic file with name nihms92008t6.jpg

Entry Aryl bromide Yield (%)
1 4-Bromobenzonitrile 83
2 4-Bromoacetophenone 85
3 4-Bromobenzotrifluoride 64
4 Methyl 4-bromobenzoate 87
5 4-Bromonitrobenzene 84
6 4-Bromoanisole 72
7 4-Bromoacetanilide 78
8 4-Bromotoluene 76
9 4-Bromobenzyl alcohol 82
10 N,N-Dimethyl 4-bromoaniline 93
11 2-Bromotoluene 82
12a 2-Bromomesitylene 81
13 1-Bromonaphthalene 82
14 2-Bromobenzonitrile 82
15 2-Bromoanisole 71
a

6% RuPhos used.