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. Author manuscript; available in PMC: 2009 Jul 27.
Published in final edited form as: Chem Commun (Camb). 2008 Aug 27;(1):20–33. doi: 10.1039/b809676g

Table 9.

Vinylation of aryl iodides using DVDS (16)

graphic file with name nihms92008t9.jpg
Entry R Pda (mol%) t/h Yield (%)
1 4-OMe 5 1.5 80
2 4-COOEt 2.5 0.5 81
3 4-OBn 5 1.5 74
4 4-t-Bu 5 4 69
5 4-CN 2.5 0.5 81
6 3-NO2 2.5 1 76
7 2-OMe 5 14 68
8 b 5 2.5 80
a

1.0 equiv. Ph3PO per Pd(dba)2.

b

1-Iodonaphthalene.