Table I.
Parameters for the functional forms of the distant-dependent dielectric “constant” obtained by fitting to the Langevin-Debye model with corrections due to Onsager-Kirkwood. The magnitudes of the partial charges are those for the atoms in DME. The parameters D and D0 are fixed to the static and optical dielectric constants of water, respectively.
| Charge (q) | Parameters for Eq. (14) | ||
|---|---|---|---|
| D | D0 | s | |
| 1 | 78.5 | 1.77 | 0.274 |
| 0.066 | 78.5 | 1.77 | 1.07 |
| 0.163 | 78.5 | 1.77 | 0.68 |
| 0.256 | 78.5 | 1.77 | 0.541 |
| 0.097 | 78.5 | 1.77 | 0.88 |