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. Author manuscript; available in PMC: 2009 Aug 3.
Published in final edited form as: J Am Chem Soc. 2004 Aug 11;126(31):9724–9734. doi: 10.1021/ja047794s

Table 2.

Activation Parameters for Alcohol Oxidation at 50 °C Using Catalyst 1

Substrate Activation Parameters
graphic file with name nihms95651t1.jpg ΔG‡ = 21.2 ± 0.7 kcal/mol
ΔH‡ = 20.1 ± 0.5 kcal/mol
ΔS‡ = −3.5 ± 1.6 eu
graphic file with name nihms95651t2.jpg ΔG‡ = 22.2 ± 1.4 kcal/mol
ΔH‡ = 25.6 ± 0.95 kcal/mol
ΔS‡ = −10.5 ± 3.0 eu
graphic file with name nihms95651t3.jpg ΔG‡ = 21.1 ± 2.5 kcal/mol
ΔH‡ = 24.9 ± 1.8 kcal/mol
ΔS‡ = 12.0 ± 5.5 eu