a, band r4, peptide CVTADLPPYPAPGK, ESI-MS/MS de novo sequencing amino acid assignment. b, band r4, peptide CVTADLPPYPA, ESI-MS/MS de novo sequencing amino acid assignment. c, band r4, peptide TLLNDYSAGK, ESI-MS/MS de novo sequencing amino acid assignment. d, band r4, peptide YGSFWDGHQVK, ESI-MS/MS de novo sequencing amino acid assignment.