TABLE 5.
Structure assignments of periodate-derived lipid A and minimal core ions by MALDIb
Molecule | Ion m/z | Fatty acidsa | No. of monosaccharides | Adduct |
---|---|---|---|---|
Lipid A | 1,309 | 3OH C14, 3OH C15, C14, C18 | 2 GlcN | M+Na |
1,069 | 3OH C14, 3OH C17, C14 | 2 GlcN | M+Na | |
1,055 | 3OH C14, 3OH C16, C14 | 2 GlcN | M+Na | |
1,027 | 2(3OH C14), C14 | 2 GlcN | M+Na | |
CC9311 LPS | 2,479 | 3OH C14, 3OH C17, C18:1, C14 | 2 GlcN, 6 Glc, 1 GalA | M+Na |
2,471 | 3OH C16, 3OH C16, C18:1, C14 | 2 GlcN, 6 Glc, 1 GalA | M+H | |
2,457 | 3OH C14, 3OH C17, C18:1, C14 | 2 GlcN, 6 Glc, 1 GalA | M+H | |
2,443 | 3OH C14, 3OH C16, C18:1, C14 | 2 GlcN, 6 Glc, 1 GalA | M+H | |
WH8102 LPS | 2,429 | 3OH C14, 3OH C16, C14, C18 | 2 GlcN, 5 Glc, 1 GalA, 1 Rha | M+H |
2,415 | 3OH C14, 3OH C15, C14, C18 | 2 GlcN, 5 Glc, 1 GalA, 1 Rha | M+H | |
2,401 | 3OH C14, 3OH C16, C14, C16 | 2 GlcN, 5 Glc, 1 GalA, 1 Rha | M+H | |
2,387 | 3OH C14, 3OH C15, C14, C16 | 2 GlcN, 5 Glc, 1 GalA, 1 Rha | M+H |
For the sake of brevity, only one potential set of fatty acids is shown per ion.
For LPS ions, the lowest-mass ion in each cluster is listed to be consistent with nominal mass predictions.