. Author manuscript; available in PMC: 2010 Jul 22.

Published in final edited form as: J Am Chem Soc. 2009 Jul 22;131(28):9608–9609. doi: 10.1021/ja901243p

Table 1.

NMR Assignments (ppm) for Valanimycin Hydrate (1)^a

Position	¹H Resonance	¹³C Resonance
1	N/A	171.337
2	4.656 (1H, dd, ³J_HH ≈ 4.9 Hz, ³J_HH ≈ 4.9 Hz)	64.580
3	4.114 (1H, dd, ²J_HH = 11.5 Hz, ³J_HH ≈ 5.0 Hz) 4.095 (1H, dd, ²J_HH = 11.5 Hz, ³J_HH ≈ 5.0 Hz)	61.855
4	4.104 (1H, dd, ²J_HH = 11.4 Hz, ³J_HH =7.2 Hz) 4.134 (1H, dd, ²J_HH = 11.4 Hz, ³J_HH = 7.8 Hz	76.875
5	2.479 (1H, nominal nonet, ³J_HH ≈ 6.9 Hz)	27.965
6	1.021 (3H, d, ³J_HH = 6.72 Hz), 1.034 (3H, d, ³J_HH = 6.72 Hz)	19.638, 19.485

Measured in CDCl₃ with shifts defined relative to TMS.