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. Author manuscript; available in PMC: 2009 Aug 14.
Published in final edited form as: Inorg Chem. 2008 Apr 1;47(9):3480–3482. doi: 10.1021/ic800148a

Table 1.

Spectroscopic comparison of CYP101, the hHO-1/H25A heme complex, and their corresponding thiolate and selenolate complexes

Complex Soret (nm) CT (nm)
H25A heme complex 399 498, 537, 620
H25A + heme (ferrous) 427 553, 585
H25A heme complex + PhSH 388 527, 651
H25A heme complex + PhSeH 388, 427 549, 583
H25A heme complex + BnSeH 427 553, 585
CYP101 417 536, 569
CYP101 + PhSH 383, 465 562
CYP101 + PhSeH 384, 472 570