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. Author manuscript; available in PMC: 2009 Aug 20.
Published in final edited form as: J Am Chem Soc. 2007 Jul 27;129(33):10282–10294. doi: 10.1021/ja072969u

Table 1.

Preliminary Survey of Disulfides and Phosphines.

graphic file with name nihms62608t1.jpg
Entry Thiol Donor Disulfide (% yield) Solvent Temp (°C) PR3 Product (% yield)
1 Me(CH2)7SH graphic file with name nihms62608t2.jpg graphic file with name nihms62608t3.jpg PhMe 110 PPh3 graphic file with name nihms62608t4.jpg
17 18 (72) 19 (71)
2 PhSH graphic file with name nihms62608t5.jpg graphic file with name nihms62608t6.jpg PhMe 110 PPh3 graphic file with name nihms62608t7.jpg
17 20 (95) 21 (69)
3 PhSH graphic file with name nihms62608t8.jpg graphic file with name nihms62608t9.jpg C6D6 rt P(NEt2)3 graphic file with name nihms62608t10.jpg
22 23 (73) 24 (80)
4 graphic file with name nihms62608t11.jpg graphic file with name nihms62608t12.jpg graphic file with name nihms62608t13.jpg CD3OD rt P(NEt2)3 graphic file with name nihms62608t14.jpg
25 26 27 (77) 28 (73)