Table 1.
PL | m/z | Ion Species | Proposed Structure sn-1/sn-2b | Relative Abundancec |
---|---|---|---|---|
Positive-Ion Mode | ||||
PC | 502.4 | M + Li | lyso-C16:0 | + |
526.4 | M + Li | lyso-C18:2 | + | |
528.4 | M + Li | lyso-C18:1 | + | |
600.5 | M + Li | C11:0/C11:0 (IS) | N/A | |
740.8 | M + Li | C16:0/C16:0 | + | |
752.7 | M + Li | C16:0/C17:1 and/or C18:1/C15:0 | + | |
754.8 | M + Li | C16:0/C17:1 | + | |
764.8 | M + Li | C16:1/C18:1 | + | |
766.8 | M + Li | C16:0/C18:1 | ++ | |
768.8 | M + Li | C16:0/C18:0 | + | |
780.6 | M + Li | C17:0/C18:1 | + | |
788.6 | M + Li | C18:2/C18:2 | + | |
790.7 | M + Li | C18:1/C18:2 | + | |
792.7 | M + Li | C18:1/C18:1 | ++ | |
794.6 | M + Li | C18:0/C18:1 | ++++ | |
806.8 | M + Na | C18:1/C18:2 | + | |
808.8 | M + Na | C18:1/C18:1 | ++ | |
814.6 | M + Li | C20:4/C18:1 | ++ | |
816.6 | M + Li | C20:4/C18:0 | + | |
SM | 709.9 | M + Li | C16:0/d18:1 | ++ |
725.7 | M + Na | C16:0/d18:1 | + | |
737.8 | M + Li | C18:0/d18:1 | + | |
Negative-Ion Mode | ||||
PC | 804.6 | M + formate | C18:1/C16:0 | + |
806.6 | M + formate | C18:0/C16:0 | + | |
820.6 | M + Cl | C18:1/C18:1 | + | |
828.6 | M + formate | C18:2/C18:1 | + | |
830.6 | M + formate | C18:1/C18:1 | + | |
832.6 | M - H | C18:0/C18:1 | + | |
PE | 578.4 | M - H | C12:0/C12:0 (IS) | N/A |
636.4 | M + NaCl - H | C12:0/C12:0 (IS) | N/A | |
646.4 | M + Na + formate - H | C12:0/C12:0 (IS) | N/A | |
714.5 | M - H | C16:0/C18:2 and/or C16:1/C18:1 | ++ | |
716.5 | M - H | C18:1/C16:0 | +++ | |
834.6 | M - H | C22:6/C22:6 (IS) | N/A | |
PG | 609.4 | M - H | C12:0/C12:0 (IS) | N/A |
707.5 | M - H | C16:0/15:0 and/or C14:0/C17:0 | + | |
719.6 | M - H | C16:0/C16:1 and/or C18:1/C14:0 | + | |
721.5 | M - H | C16:0/16:0 and/or C18:0/C14:0 | +++ | |
733.5 | M - H | C16:0/C17:1 and/or C18:1/C15:0 | + | |
735.5 | M - H | C16:0/C17:0 and/or C15:0/C18:0 | + | |
745.5 | M - H | C18:2/C16:0 and/or C16:1/C18:1 | + | |
747.5 | M - H | C18:1/C16:0 | ++++ | |
749.5 | M - H | C18:0/C16:0 | ++++ | |
761.5 | M - H | C18:1/C17:0 | + | |
763.6 | M - H | C18:0/C17:0 and/or C19:0/C16:0 | + | |
771.5 | M - H | C18:1/C18:2 | + | |
773.5 | M - H | C18:1/C18:1 | + | |
775.5 | M - H | C18:0/C18:1 | + | |
777.6 | M - H | C16:0/20:0 and/or C18:0/C18:0 | + | |
789.5 | M + Na + formate – H | C16:0/C16:0, C18:0/C14:0, and/or C15:0/C17:0 | + | |
817.5 | M + Na + formate – H | C18:0/C16:0 | + | |
PI | 809.5 | M - H | C16:0/C16:0 | + |
835.5 | M - H | C18:1/C16:0 | + |
Phospholipid species were identified by MS-MS analysis in positive- and negative-ion modes.
Relative abundance is designated by the peak height: ++++, up to 100%; +++, up to 75%; ++, up to 50%; +, 10% or less. IS, internal standard.
Relative abundances for each sample were similar and therefore only the peak heights for trophozoites are shown.
N/A, not applicable.