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Water–water correlations at different interfaces. (A) Water oxygen–oxygen pair correlations, gww(r), near −CH3 and −OH surfaces measured in a 0.1 nm-thick slab parallel to the interface located at the half-density plane of water. (B) gww(r) for r>1 nm. Water correlations measured similarly at a vapor–liquid interface and in bulk water are shown for reference. Because of the quasi-two-dimensional nature of gww(r), cylindrical shell normalization volumes were used in the calculations.
