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. 2009 Aug 21;106(36):15249–15253. doi: 10.1073/pnas.0907616106

Table 1.

Fitted values for Kd, Bmax, b, and c from cloud-point temperature measurements and literature values for some thermodynamic properties

Anion Vi0 (cm3/mol) ΔGhydr (KJ/mol) α (10−30 m3) σair/water (mN L/mM) Kd (M) Bmax (°C) b (M−1) c (°C/mol) σlysozyme/water (mN L/mM)
ClO4− 49.6 −214 5.062 1.4 0.10 60.1 −7.02 −17.0 −2.7
SCN− 41.2 −287 6.739 0.5 0.10 61.1 −5.35 −31.4 −5.0
I− 41.7 −283 7.512 1.0 0.09 55.5 −4.89 −26.3 −4.2
NO3− 34.5 −306 4.134 1.1 0.10 42.9 −3.21 −0.9 −0.1
Br− 30.2 −321 4.852 1.3 0.18 43.8 −1.75 −8.7 −1.4
Cl− 23.3 −347 3.421 1.6 0.12 28.1 −0.10 10.3 1.6

The estimated interfacial tension increments for the anions at the protein/water interface (σprotein/water) are also listed. Vi0, ΔGhydr, and α data are from ref. 43; σ data are from ref. 59. Note that 10−30 m3 = 1 Å3