TABLE 4.

Thermodynamic analysis of binding of bicyclooctane-based guests with CB[7]. See Table 3 for definitions

					Changes in Mean Energy Terms
	Q1,Q2	$\Delta G_{clc}^o$	$\Delta \langle U+W\rangle$	$-T\Delta S_{cfg}^o$	ΔUvdW	ΔUC	ΔWel	ΔEel	ΔUval	ΔWnp	$\frac{\Delta G_{clc}^o}{\Delta \langle U+W\rangle }$
B	0, 0	-14.5	-22.6	8.1	-28.9	1.0	7.8	8.8	-0.3	-2.2	0.64
B1	0, 0	-14.8	-27.2	12.4	-31.6	-3.3	9.7	6.4	0.4	-2.5	0.54
B2	0, 0	-12.8	-29.6	16.8	-34.6	-8.1	14.3	6.2	1.4	-2.7	0.43
B3	0, 0	-8.6	-20.7	12.1	-32.0	-1.1	13.9	12.8	1.1	-2.6	0.42
B4	+1, 0	-22.5	-34.2	11.7	-30.0	-78.0	75.1	-2.9	1.2	-2.5	0.66
B5	+1,+1	-25.6	-37.6	12.0	-31.8	-162.1	155.3	-6.8	3.8	-2.7	068
B6	+1, 0	-21.3	-36.0	14.7	-36.1	-68.2	71.0	2.8	0.1	-2.8	0.59
B7	+1,+1	-24.5	-42.2	17.7	-41.9	-138.0	140.4	2.4	0.6	-3.3	0.58
B8	+2, 0	-23.5	-35.6	12.1	-34.2	-123.2	122.1	-1.0	2.3	-2.8	0.66
B9	+2,+2	-21.0	-35.3	14.3	-38.5	-244.2	245.5	1.3	5.2	-3.3	0.59
B10	+2, 0	-23.1	-38.2	15.1	-35.2	-123.7	118.9	-4.8	4.7	-2.9	0.61
B11	+2,+2	-19.9	-41.4	21.5	-42.0	-241.1	232.0	-9.1	13.5	-3.8	0.48
B12	+3, 0	-21.5	-33.0	11.5	-34.8	-163.1	159.9	-3.2	7.9	-2.9	0.65
B13	+3,+3	-18.7	-36.1	17.5	-37.3	-313.9	313.0	-0.9	5.3	-3.2	0.52