Figure 1.
(a) Schematic of two-step QD-FRET. Excitation of the QD donor drives stepwise energy transfer (E12) through the nuclear dye (ND) which serves as the first acceptor/donor (or relay) for energy transfer to the second acceptor Cy5 (E23). (b) Plasmid DNA is double-labeled with QD and nuclear dyes before complexation with a Cy5-labeled cationic polymer to form nanocomplexes by self-assembly. Three distinct states of plasmid DNA (pDNA): (I) condensed within a nanocomplex, (II) released and intact, and (III) degraded, are distinguished by relative ND and Cy5 emission and calculated E12 and E23 efficiencies.