. Author manuscript; available in PMC: 2009 Oct 15.

Published in final edited form as: J Am Chem Soc. 2008 Sep 18;130(41):13552–13554. doi: 10.1021/ja8055358

Table 4.

Mono-arylation of Methylamine^a

ArCl (1 mmol), 2M MeNH₂ in THF (2.0 mmol), 6 (1 mol %), NaOt-Bu (1.2 mmol).

0.3 mol % 6.

0.1 mol % 6.

35:1 mixture of monoarylation to diarylation.

17 h reaction time.

Selectivities determined by GC.