Table 1.
Output parameters from modeling with hard-sphere structure factors
Concentration (mg/ml) | NaCl (M) | Volume fraction | Interaction radius (Å) | χ2 | |
---|---|---|---|---|---|
Phy | 85 | 0.3 | 0.157 ± 4 × 10−4 | 32.40 + 0.06 | 56 |
87 | 1.0 | 0.145 ± 3 × 10−4 | 32.00 + 0.05 | 17 | |
160 | 0.3 | 0.243 ± 5 × 10−4 | 31.20 + 0.05 | 99 | |
152 | 1.0 | 0.239 ± 5 × 10−4 | 31.10 + 0.05 | 65 | |
dgPhy | 50 | 0.3 | 0.0383 ± 6 × 10−4 | 27.50 + 0.15 | 43 |
52 | 1.0 | 0.0330 ± 7 × 10−4 | 27.20 + 0.12 | 38 | |
79 | 0.3 | 0.0863 ± 5 × 10−4 | 27.90 + 0.11 | 31 | |
80 | 1.0 | 0.0773 ± 6 × 10−4 | 26.80 + 0.16 | 53 |
The excluded volume fraction and the interaction radius were used as fitting parameters. Some of the listed χ2 values are a bit high, but as can be seen from Fig. 1, the deviations of the experimental data from the model fits are primarily found above 0.15 Å−1, and for that reason, this major part of the deviation does not influence the precision of the calculated parameters.