Table III.
Sample | No., Type of Ligands per Shell ± se | Distance ± se | 2σi2 ± 2σ sd | EF ± se | FI (No. of Variables) |
---|---|---|---|---|---|
Å | Å2 | ||||
Cu-glutathionea | 3.6 ± 0.2, S | 2.260 ± 0.002 | 0.006 ± 0.001 | −11.5 ± 0.4 | 0.142 |
4.5 ± 0.6, Cu | 2.710 ± 0.005 | 0.021 ± 0.002 | |||
Cu(II)-His | 5.0 ± 0.8, Nb | 2.000 ± 0.006* | 0.008 ± 0.001* | −10.5 ± 0.6 | 0.403 |
0.4 ± 0.8, O | 2.000 ± 0.006* | 0.008 ± 0.001* | |||
Cu(II)-NA, pH 4 | 3.8 ± 0.3, N/O | 1.980 ± 0.003 | 0.009 ± 0.001 | −9.8 ± 0.4 | 0.251 |
3.7 ± 0.8, C | 2.862 ± 0.012 | 0.011 ± 0.004* | |||
5.0 ± 1.3, C | 3.403 ± 0.015 | 0.011 ± 0.004* | |||
Cu(II)-NA, pH 7 | 5.6 ± 0.3, N/O | 1.975 ± 0.003 | 0.006 ± 0.001 | −9.4 ± 0.5 | 0.305 |
4.1 ± 0.8, C | 2.837 ± 0.010 | 0.006 ± 0.003* | |||
4.7 ±1.2, C | 3.394 ± 0.014 | 0.006 ± 0.003* | |||
Cu(II)-Pro, pH 7 | 5.2 ± 0.3, N/O | 1.957 ± 0.004 | 0.008 ± 0.001 | −12.5 ± 0.5 | 0.285 |
Mixture of Cu(I) and Cu(II) as obtained by the preparation method.
Bound to His.