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. Author manuscript; available in PMC: 2010 Jul 29.
Published in final edited form as: J Am Chem Soc. 2009 Jul 29;131(29):10308–10319. doi: 10.1021/ja902716d

Scheme 3.

Scheme 3

Degenerate electronic ground state structures of the CuII-hydroperoxo and CuII-hydroxyl oxidant species proposed for direct substrate oxidation/product release. Please note, copper domain residues were omitted for clarity. Refer to text for more detail.