. Author manuscript; available in PMC: 2010 Jul 29.

Published in final edited form as: J Am Chem Soc. 2009 Jul 29;131(29):10308–10319. doi: 10.1021/ja902716d

Table 1.

Kinetic parameters determined from the steady-state preferred bi-substrate Michaelis-Menten equation 3.

	V_MAX (s^-1)	K_D,BIAA (mM)	K_{M, O2} (mM)	(V_MAX/K_M)_O2 (M^-1s^-1)	^DK_D,BIAA	^D(V_MAX)	^D(V_MAX/K_M)_O2
Protiated	4.75 (0.19)	758.18 (133.42)	95.37 (12.18)	4.98E+04 (5.03E+03)	2.06 (0.52)	0.84 (.08)	5.78 (0.71)
Deuterated	5.68 (0.46)	367.95 (66.58)	658.08 (95.02)	8.63E+03 (6.02E+02)	2.06 (0.52)	0.84 (.08)	5.78 (0.71)