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. Author manuscript; available in PMC: 2010 Jan 14.

Published in final edited form as: J Am Chem Soc. 2009 Jan 14;131(1):78–88. doi: 10.1021/ja0781893

Comparison between experimental conversion vs. time data, and results obtained by numerically integrating equation 14 with k_app = 0.2 M⁻¹•s⁻¹ for different ratios of k_f : k_r (= Cu_active:Cu_inactive). Conditions: [ArI]_o = 0.4 M, [Cu_inactive]_o = 0.02 M, a) experimental [3] = 0.02 M, b) experimental [3] = 0.29 M.