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. 1998 May 26;95(11):5960–5964. doi: 10.1073/pnas.95.11.5960

Table 1.

Molecules, dilution factors, T values, and Nloc values

Molecule σ T Nloc Molecule σ T Nloc


Methane 1 0.005 Cyclopentene 0.003 0.89 5.7
Ethylene oxide 0.5 0.015 0.16 0.008 0.70 5.0–5.1
0.7 0.018 0.12 0.01 0.35 3.1–4.5
0.8 0.01 0.10 0.01 0.67 2.9
Cyclopropane 0.7 0.0035 2.4 0.02 0.4 2.3–3.9
0.3 0.0174 1.3 2,3-Dihydrofuran 0.5 0.2 5.3
Ethane 1 0.01 1.1 Tetrahydrofuran 0.01 0.75 2.2–4.0
0.8 0.02 2.9 Cyclopentanone 0.003 1.3 2.6–5.5
Oxetane 1 0.13 1.84 Norbornene 0.01 1.6 6.8–12
1 0.18 0.22 0.1 2.6 10
1 0.22 0.29 Cyclopentane 0.01 1.7 6.1–9.0
1 0.22 0.14 0.02 1.4 6.2
Methyl formate 0.3 0.05 1.67 0.09 0.5 3.2–5.2
Propylene oxide 0.02 0.5 2.4 Cyclohexane 0.005 1.3 8.1–12
0.02 0.6 1.8 0.01 2.2 9.4
Fluorobenzene 1 0.9 2.2–3.7 0.01 1.1
Cyclobutanone 0.4 0.24 1.3–3.2 Isobutane 0.05 0.2 3.8
0.3 0.4 1.5 2-Methyltetrahydrofuran 0.003 1.2 11–13
Propane 0.2 0.08 3.5 0.004 1.5 13
0.4 0.26 0.4–1.1

From the data of Stewart and McDonald (11), modes other than C—H stretches and results where σ had only an upper bound were excluded. The mean value of the Nloc is about an order of magnitude larger than T; the correlation between the two is shown in Fig. 1. Where Stewart and McDonald listed a group of bands under one frequency, ranges are given for Nloc indicating the minimum and maximum values obtained numerically for the bands near that frequency.