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. Author manuscript; available in PMC: 2010 Jan 1.
Published in final edited form as: Angew Chem Int Ed Engl. 2009;48(19):3482–3485. doi: 10.1002/anie.200900112

Table 2.

DBU mediated incorporation of 11CO2: scopea

graphic file with name nihms-136491-t0002.jpg

entry product %yieldb
1 graphic file with name nihms-136491-t0003.jpg 60
2 graphic file with name nihms-136491-t0004.jpg 48
3 graphic file with name nihms-136491-t0005.jpg 16
4 graphic file with name nihms-136491-t0006.jpg 7
16c
5 graphic file with name nihms-136491-t0007.jpg 4
6 graphic file with name nihms-136491-t0008.jpg 77±8d
33c
7 graphic file with name nihms-136491-t0009.jpg 33
11c
8 graphic file with name nihms-136491-t0010.jpg 12
69c
9 graphic file with name nihms-136491-t0011.jpg 6
10 graphic file with name nihms-136491-t0012.jpg <1
[a]

All reactions were carried out with 100 mM of amine, alkyl chloride, and DBU in 300 μL of DMF.

[b]

Average radiochemical yield of two or more reactions.

[c]

Radiochemical yield for the corresponding alkyl bromide.

[d]

mean ± stdev (n = 10).