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. Author manuscript; available in PMC: 2009 Oct 6.
Published in final edited form as: Org Lett. 2007 Feb 1;9(3):457–460. doi: 10.1021/ol062808f

Table 3.

Palladium-Catalyzed Carboamination of Aryl Triflatesa

entry amine aryl triflate product dr yieldb
1 graphic file with name nihms-63833-t0042.jpg graphic file with name nihms-63833-t0043.jpg graphic file with name nihms-63833-t0044.jpg — 67
0c
2 graphic file with name nihms-63833-t0045.jpg graphic file with name nihms-63833-t0046.jpg graphic file with name nihms-63833-t0047.jpg — 74
3 graphic file with name nihms-63833-t0048.jpg graphic file with name nihms-63833-t0049.jpg graphic file with name nihms-63833-t0050.jpg 12:01 70
4 graphic file with name nihms-63833-t0051.jpg graphic file with name nihms-63833-t0052.jpg graphic file with name nihms-63833-t0053.jpg >20:1 64
a

Conditions: 1.0 equiv amine, 1.2 equiv ArOTf, 2.3 equiv K3PO4, 4 mol % Pd(OAc)2, 8 mol % Dpe-phos, dioxane (0.25 M), 100 °C.

b

Yield refers to average isolated yield obtained in two or more experiments.

c

NaOtBu used in place of K3PO4.