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. 2009 May 7;42(13):4681–4689. doi: 10.1021/ma900614j

Table 1. Results from Fits to Dsoln/D0 of the Three Probes in Linear PDMS Solutiona.

model   octane bodipy terrylene
free-volume, Bd 0.75 ± 0.1 0.96 ± 0.06 2.48 ± 0.2
eq 2 fpb 0.25 ± 0.05
Phillies, α 1.7 ± 0.1 2.9 ± 0.2 2.9 ± 0.3
eq 4 ν 1.85 ± 0.1 2.4 ± 0.1 1.1 ± 0.1
Petit, a 3.3 ± 0.3 9.4 ± 1.3 10.3 ± 3.2
eq 5 ν 1.2 ± 0.1 1.8 ± 0.1 0.87 ± 0.1
a

Note that all results are dimensionless.

b

Obtained from a simultaneous fit of all three data sets using a common fp′ and a probe-specific B′ .