Table 1. Results from Fits to Dsoln/D0 of the Three Probes in Linear PDMS Solutiona.
model | octane | bodipy | terrylene | |
---|---|---|---|---|
free-volume, | Bd′ | 0.75 ± 0.1 | 0.96 ± 0.06 | 2.48 ± 0.2 |
eq 2 | fp′b | → | 0.25 ± 0.05 | ← |
Phillies, | α | 1.7 ± 0.1 | 2.9 ± 0.2 | 2.9 ± 0.3 |
eq 4 | ν | 1.85 ± 0.1 | 2.4 ± 0.1 | 1.1 ± 0.1 |
Petit, | a | 3.3 ± 0.3 | 9.4 ± 1.3 | 10.3 ± 3.2 |
eq 5 | ν′ | 1.2 ± 0.1 | 1.8 ± 0.1 | 0.87 ± 0.1 |
Note that all results are dimensionless.
Obtained from a simultaneous fit of all three data sets using a common fp′ and a probe-specific B′ .