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. Author manuscript; available in PMC: 2010 Oct 7.
Published in final edited form as: J Am Chem Soc. 2009 Oct 7;131(39):13963–13971. doi: 10.1021/ja905081x

Figure 3.

Figure 3

Computed Hammond shifts in transition structure as illustrated by the difference in acceptor and donor distance from the transferring hydrogen (ΔR) with increasing endroergicity of reaction.